Cartap hydrochloride|RONAS CHEMICALS IND.CO.,LTD.

MSDS of Cartap hydrochloride

Material Safety Data Sheets of Cartap hydrochloride

1.Identification of the substance
ISO Common Name: Cartap
Trade Name: Cartap Hydrochloride
Synonyms: Carbamic acid, thio-S,S-[2-(dimethylamino)trimethylene]ester, Monohydrochloride
CAS No.: 15263-53-2
Molecular Weight:273.66
Molecular Formula: C7H16N3O2S2Cl
Structure:
Usage: herbicide

2.Composition / information on ingredients
Chemical name CAS No. % Symbol R-Phrases
1) AMMONIUM SULFATE 50 F R11
2) Cartap HCl 22042-59-7 50 T+, N R24, R26/28, R36/37,R55, R57

3.Hazards identification
Physical/chemical hazards : Not applicable.
Human health hazards: Toxic in contact with skin.Very toxic by inhalation and if swallowed.
Irritating to eyes and respiratory system.

4.First-aid measures
First-Aid measures

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention immediately.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything
by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get
medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly
clean shoes before reuse. Get medical attention immediately.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of
water for at least 15 minutes. Cold water may be used. Get medical attention.
Effects and symptoms:
Inhalation: May be fatal if inhaled.
Ingestion: Very hazardous in case of ingestion. May be fatal if swallowed.
Eye Contact: Hazardous in case of eye contact (irritant, corrosive). Eye contact can result in corneal damage or blindness.
Aggravating conditions: Repeated exposure to a highly toxic material may produce general deterioration of health by an
accumulation in one or many human organs.

5. Fire-fighting measures
Extinguishing Media
Suitable: SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Hazardous thermal (de)composition: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), sulfur oxides (SO2, SO3...), halogenated compounds, hydrogen chloride.
Special fire-fighting procedures: Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.
Protection of fire-fighters: Be sure to use an approved/certified respirator or equivalent.

6.Accidental release measures
Personal precautions:Dust protection mask Gloves. Safety glasses.
Environmental Precautions and Clean-up Methods: Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed.
Eliminate all ignition sources. Call for assistance on disposal. Neutralize the residue with a dilute solution of sodium carbonate.

7. Handling and storage
Handling: Keep locked up. Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty
containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing
material. Do not ingest. Do not breathe dust. Avoid contact with eyes. Never add water to this product.
If ingested, seek medical advice immediately and show the container or the label. Keep away from
incompatibles such as oxidizing agents.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use: Use original container.

8. Exposure controls/personal protection
Engineering measures: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels
below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to
keep exposure to airborne contaminants below the exposure limit.
Hygiene measures: Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, using lavatory, and at the end of day.

Occupational Exposure Limits
Ingredient Name Occupational Exposure Limits
1) Trade Secret ACGIH (United States, 1994). TWA: 20 mg/m3 Form: Dust
2) Cartap HCl ACGIH (United States, 1993). TWA: 1 mg/m3 Form: Dust
Personal protective equipment
Respiratory system : Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate.
Skin and body: Lab coat.
Hands: Gloves.
Eyes: Splash goggles.

9. Physical and chemical properties
Physical state: Solid.
Color: Light.
Odor: Slight.
Melting Point: 179degree C (354.2¡ãF) based on data for: 1,3-bis(carbamoylthio)-2-(N,N-dimethylamino) Propane
Hydrochloride.
Density: Not available.
Solubility: Easily soluble in hot water. Soluble in cold water.
Octanol/water partition coefficient: The product is much more soluble in water.
PH: Acidic.
Flash point: Not available.
Flammability (solid, gas): Highly flammable in presence of oxidizing materials.
Flammable in presence of open flames, sparks and static discharge.
Slightly flammable to flammable in presence of heat.
Explosive properties: Risks of explosion of the product in presence of mechanical impact: Not available.
Extremely explosive in presence of open flames, sparks and static discharge.

10. Stability and reactivity
Stability: The product is stable.
Materials to avoid: Highly reactive with oxidizing agents. Slightly reactive to reactive with alkalis.
Hazardous Decomposition Products: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), sulfur oxides (SO2, SO3...),
halogenated compounds, hydrogen chloride.

11. Toxicological information
Local effects
Acute toxicity: Acute oral toxicity (LD50): 340 mg/kg [Rat]. (1,3-bis(carbamoylthio)-2-(N,N-dimethylamino) Propane
Hydrochloride).
Chronic toxicity: Repeated exposure to a highly toxic material may produce general deterioration of health by an
accumulation in one or many human organs.

12. Ecological information
Ecotoxicity: Fish LC50 for carp 1.6 mg/l (24 h) and 1.0 mg/l (48 h). Other aquatic spp. LC50 (24 h) for Moina macrocopa 12.5-25 mg/l. Bees Moderately toxic to honeybees.

13. Disposal considerations
Methods of disposal; Waste of residues; Contaminated packaging: Waste must be disposed of in accordance with federal, state and local environmental control regulations.

14. Transport information
International transport regulations
UN number: UN2811
Land - Road/Railway
Proper shipping name: Toxic solid, organic, n.o.s. (1,3-bis(carbamoylthio)-2-(N,N-dimethylamino) Propane Hydrochloride)
ADR/RID Class: 6.1
Packing Group: III
Sea
Proper shipping name: Toxic solid, organic, n.o.s. (1,3-bis(carbamoylthio)-2-(N,N-dimethylamino) Propane Hydrochloride)
ADR/RID Class: 6.1
Packing Group: III

15. Regulatory information
Risk Phrases: R24- Toxic in contact with skin.
R26/28- Very toxic by inhalation and if swallowed.
R36/37- Irritating to eyes and respiratory system.
Safety Phrases: S1/2- Keep locked up and out of the reach of children.
S28- After contact with skin, wash immediately with plenty of [***].
S36/37- Wear suitable protective clothing and gloves.
S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
S63- In case of accident by inhalation: remove casualty to fresh air and keep at rest.
Contains: - 1,3-bis(carbamoylthio)-2-(N,N-dimethylamino) Propane Hydrochloride

16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.