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Material
Safety Data Sheets of Ammonium bicarbonate
Section 1 - Chemical Product and Company Identification
MSDS Name: Ammonium Bicarbonate
Synonyms:
Ammonium hydrogencarbonate
Section 2 - Composition, Information on Ingredients
CAS#----------- Chemical Name ---------Percent -------EINECS/ELINCS
1066-33-7 ----Ammonium bicarbonate- 100 -----------213-911-5
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: colorless to white solid. Causes eye and skin irritation.
May cause digestive
tract irritation. Causes respiratory tract irritation. Irritant.
Harmful if swallowed.
Respiratory system, eyes, skin.
Warning!
Target Organs:
Potential Health Effects
Eye:Causes
eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. May be harmful if absorbed through the
skin.
Ingestion:Harmful
if swallowed. May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Can produce delayed pulmonary edema.
Chronic:No
information found.
Section 4 - First Aid Measures
Eyes:Immediately
flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the
upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least
15 minutes while removing
contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce
vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls
of milk or water. Wash mouth out
with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical
aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:Treat
symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information:As
in any fire, wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear.
During a fire, irritating and highly,toxic
gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use
water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point:Not
applicable.
Autoignition Temperature:Not
applicable.
Explosion Limits, Lower:Not
applicable.
Upper:Not
applicable.
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
General Information:Use
proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up
spills immediately, observing precautions in the Protective Equipment
section. Avoid generating dusty
conditions. Provide ventilation.
Section 7 - Handling and Storage
Handling:Minimize
dust generation and accumulation. Avoid breathing dust, vapor,
mist, or gas.
Avoid contact with eyes, skin, and clothing. Keep container tightly
closed. Avoid ingestion and
inhalation. Use with adequate ventilation. Wash clothing before
reuse.
Storage:Store
in a cool, dry place. Store in a tightly closed container.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls:Facilities
storing or utilizing this material should be equipped with an
eyewash,facility
and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
Chemical Name ------------ACGIH ----------NIOSH------- OSHA -
Final PELs
Ammonium bicarbonate--none listed-- none listed ---none listed
OSHA Vacated PELs:Ammonium
bicarbonate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles
as described by OSHA's eye
and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:Wear
appropriate protective clothing to prevent skin exposure.
Clothing:Wear
appropriate protective gloves to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134
or European Standard
EN 149. Always use a NIOSH or European Standard EN 149 approved
respirator when necessary.
Section 9 - Physical and Chemical Properties
Physical State:Solid
Appearance:colorless
to white
Odor:ammonia-like
- weak odor
pH:7.8
@ 0.1N.
Vapor Pressure:
60 mm Hg @ 25 C
Vapor Density:
Not available.
Evaporation Rate:
Not available.
Viscosity:
Not available.
Boiling Point:Decomposes.
Freezing/Melting Point:
140 deg F
Decomposition Temperature:
140 deg F
Solubility:17.4
% @ 20C in water.
Specific Gravity/Density:1.586
Molecular Formula:NH4HCO3
Molecular Weight:79.0399
Section 10 - Stability and Reactivity
Chemical Stability:Stable
at room temperature in closed containers under normal storage
and
handling conditions.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:Oxidizing
agents, strong acids, nitrates, nitrites, alkalis.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, ammonia.
Hazardous Polymerization:Has
not been reported.
Section 11 - Toxicological Information
RTECS#: CAS#1066-33-7:
BO8600000
LD50/LC50:Not
available.
Carcinogenicity:
CAS# 1066-33-7: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology:No
information available.
Teratogenicity:No
information available.
Reproductive Effects:No
information available.
Neurotoxicity:No
information available.
Mutagenicity:No
information available.
Other Studies:No
data available.
Section 12 - Ecological Information
No information available.
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical
is classified as a hazardous
waste. US EPA guidelines for the classification determination
are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous
waste regulations to ensure
complete and accurate classification.
RCRA P-Series:None
listed.
RCRA U-Series:None
listed.
Section 14 - Transport Information
US DOT IATA RID/ADR IMO Canada TDG
No
information available.
Shipping Name: No information available.
Hazard Class:
UN Number:
Packing Group:
Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS#
1066-33-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting
List.
Chemical Test Rules
None
of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None
of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None
of the chemicals in this material have a SNUR under TSCA.
SARA
CERCLA Hazardous Substances and corresponding RQs
CAS#
1066-33-7: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None
of the chemicals in this product have a TPQ.
Section 313
No
chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This
material does not contain any Class 1,Ozone
depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS#
1066-33-7 is listed as a Hazardous Substance under the CWA. None
of the chemicals in this
product are listed as Priority Pollutants under the CWA. None
of the chemicals in this product are listed
as Toxic Pollutants under the CWA.
OSHA:None
of the chemicals in this product are considered highly hazardous
by OSHA.
STATE
CAS#
1066-33-7 can be found on the following state right to know lists:
California, New Jersey,
Pennsylvania, Massachusetts.
California No Significant Risk Level: None of the chemicals in
this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS#
1066-33-7: 1
Canada - DSL/NDSL
CAS#
1066-33-7 is listed on Canada's DSL List.
Canada - WHMIS
This
product has a WHMIS classification of D2B.
Canadian Ingredient Disclosure List
Exposure Limits
Section 16 - Additional Information
The information above is believed to be accurate and represents
the best information currently available to us. However, we make
no
warranty of merchantability or any other warranty, express or
implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations
to determine the suitability of the information for their particular
purposes. In no event shall Fisher be liable for any claims, losses,
or damages of any third party or for lost profits or any special,
indirect, incidental, consequential or exemplary damages, howsoever
arising, even if Fisher has been advised of the possibility of
such
damages.
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