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Material
Safety Data Sheets of Potassium Nitrate
1. Product Identification
Synonyms: Saltpeter; niter; Nitric acid, potassium salt
CAS No.: 7757-79-1
Molecular Weight: 101.1
Chemical Formula: KNO3
2. Composition/Information on Ingredients
| Ingredient |
CAS
No |
Percent |
Hazardous
|
| Potassium
Nitrate |
7757-79-1 |
99
- 100% |
Yes
|
3. Hazards Identification
Emergency Overview
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DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE
FIRE. HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN.
CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.
SAF-T-DATA(tm)
Ratings (Provided here for your convenience)
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Health Rating: 2 - Moderate
Flammability Rating: 0 - None
Reactivity Rating: 3 - Severe (Oxidizer)
Contact Rating: 2 - Moderate (Life)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON;
VENT HOOD; PROPER GLOVES
Storage Color Code: Yellow (Reactive)
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Potential
Health Effects
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Inhalation:
Causes irritation to the respiratory tract. Symptoms may include
coughing, shortness of breath.
Ingestion: Causes irritation to the gastrointestinal tract. Symptoms
may include nausea, vomiting and diarrhea. May cause gastroenteritis
and abdominal pains. Purging and diuresis can be expected. Rare
cases of nitrates being converted to the more toxic nitrites have
been reported, mostly with infants.
Skin Contact: Causes irritation to skin. Symptoms include redness,
itching, and pain.
Eye Contact: Causes irritation, redness, and pain.
Chronic Exposure: Under some circumstances methemoglobinemia occurs
in individuals when the nitrate is converted by bacteria in the
stomach to nitrite. Nausea, vomiting, dizziness, rapid heart beat,
irregular breathing, convulsions, coma, and death can occur should
this conversion take place. Chronic exposure to nitrites may cause
anemia and adverse effects to kidney.
Aggravation of Pre-existing Conditions: No information found.
4. First Aid Measures
Inhalation: Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical
attention.
Ingestion: Induce vomiting immediately as directed by medical
personnel. Never give anything by mouth to an unconscious person.
Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention. Wash clothing before reuse. Thoroughly
clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at
least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.
5. Fire Fighting Measures
Fire: Not combustible, but substance is a strong oxidizer and
its heat of reaction with reducing agents or combustibles may
cause ignition.
Explosion: Some nitrates may explode when shocked, exposed to
heat or flame, or by spontaneous chemical reaction. Sealed containers
may rupture when heated. Sensitive to mechanical impact.
Fire Extinguishing Media: Dry chemical, carbon dioxide, Halon,
water spray, or fog. If water is used, apply from as far a distance
as possible. Water spray may be used to keep fire exposed containers
cool. Do not allow water runoff to enter sewers or waterways.
Special Information: Wear full protective clothing and breathing
equipment for high-intensity fire or potential explosion conditions.
This oxidizing material can increase the flammability of adjacent
combustible materials.
6. Accidental Release Measures
Remove all sources of ignition. Ventilate area of leak or spill.
Wear appropriate personal protective equipment as specified in
Section 8. Spills: Clean up spills in a manner that does not disperse
dust into the air. Use non-sparking tools and equipment. Reduce
airborne dust and prevent scattering by moistening with water.
Pick up spill for recovery or disposal and place in a closed container.
7. Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated
area. Protect against physical damage and moisture. Isolate from
any source of heat or ignition. Avoid storage on wood floors.
Separate from incompatibles, combustibles, organic or other readily
oxidizable materials. Containers of this material may be hazardous
when empty since they retain product residues (dust, solids);
observe all warnings and precautions listed for the product.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is
recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control
the emissions of the contaminant at its source, preventing dispersion
of it into the general work area. Please refer to the ACGIH document,
Industrial Ventilation, A Manual of Recommended Practices, most
recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where
exposure to dust or mist is apparent and engineering controls
are not feasible, a particulate respirator (NIOSH type N95 or
better filters) may be worn. If oil particles (e.g. lubricants,
cutting fluids, glycerine, etc.) are present, use a NIOSH type
R or P filter. For emergencies or instances where the exposure
levels are not known, use a full-face positive-pressure, air-supplied
respirator. WARNING: Air-purifying respirators do not protect
workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including
boots, gloves, lab coat, apron or coveralls, as appropriate, to
prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield
where dusting or splashing of solutions is possible. Maintain
eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance: White crystals.
Odor: Odorless.
Solubility: 36 gm/l00 ml water
Specific Gravity: 2.1
PH: ca. 7
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 400C (752F)
Melting Point: 333C (631F)
Vapor Density (Air=1): 3.00
Vapor Pressure (mm Hg): Negligible @ 20C
Evaporation Rate (BuAc=1): No information found.
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Oxides of nitrogen and toxic
metal fumes may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Heavy metals, phosphites, organic compounds,
carbonaceous materials, strong acids, and many other substances.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.
11. Toxicological Information
Oral rat LD50: 3750 mg/kg. Investigated as a mutagen, reproductive
effector.
12. Ecological Information
Environmental Fate: No information found.
Environmental Toxicity: No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be handled
as hazardous waste and sent to a RCRA approved waste facility.
Processing, use or contamination of this product may change the
waste management options. State and local disposal regulations
may differ from federal disposal regulations. Dispose of container
and unused contents in accordance with federal, state and local
requirements.
14. Transport Information
Domestic (Land, D.O.T.)
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Proper Shipping Name: POTASSIUM NITRATE
Hazard Class: 5.1
UN/NA: UN1486
Packing Group: III
Information reported for product/size: 50KG
International
(Water, I.M.O.)
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Proper Shipping Name: POTASSIUM NITRATE
Hazard Class: 5.1
UN/NA: UN1486
Packing Group: III
Information reported for product/size: 50KG
15. Regulatory Information
Australian Hazchem Code: 1[T]
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of
the Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
16. Other Information
NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Other: Oxidizer
Label Hazard Warning:
DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE
FIRE. HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN.
CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.
Label Precautions:
Keep from contact with clothing and other combustible materials.
Store in a tightly closed container.
Do not store near combustible materials.
Remove and wash contaminated clothing promptly.
Avoid contact with eyes, skin and clothing.
Avoid breathing dust.
Keep container closed.
Use only with adequate ventilation.
Wash thoroughly after handling.
Label First Aid: If swallowed, induce vomiting immediately as
directed by medical personnel. Never give anything by mouth to
an unconscious person. If inhaled, remove to fresh air. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. In case of contact, immediately flush eyes or skin
with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Wash clothing before reuse. In all cases,
get medical attention.
Product Use: Laboratory Reagent.
Revision Information: MSDS Section(s) changed since last revision
of document include: 3.
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