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Material
Safety Data Sheets of Calcium Gluconate
CALCIUM GLUCONATE
1.
Product Identification
Synonyms: D-Gluconic acid, calcium salt (2:1); Glucobiogen; Calciofon.
CAS No.: 299-28-5
Molecular Weight: 430.38
Chemical Formula: [CH2OH(CHOH)4COO]2Ca
2.
Composition/Information on Ingredients
Ingredient-----------
CAS No ----Percent-----
Hazardous
Calcium Gluconate --299-28-5---
98 - 100% ---Yes
3.
Hazards Identification
Emergency Overview
As part of good industrial and personal hygiene and safety procedure,
avoid all unnecessary exposure to the chemical substance and ensure
prompt removal from skin, eyes and clothing.
J.T.
Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience)
Health Rating: 1 - Slight
Flammability Rating: 0 - None
Reactivity Rating: 0 - None
Contact Rating: 1 - Slight
Lab Protective Equip: GOGGLES; LAB COAT
Storage Color Code: Orange (General Storage)
Potential
Health Effects
Inhalation:
Not expected to be a health hazard.
Ingestion: Large oral doses may cause irritation to the gastrointestinal
tract.
Skin Contact: Not expected to be a health hazard from skin exposure.
Eye Contact: Not expected to be a health hazard.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.
4.
First Aid Measures
Inhalation: Remove to fresh air. Get medical attention for any
breathing difficulty.
Ingestion: If large amounts were swallowed, give water to drink
and get medical advice.
Skin Contact: Wash exposed area with soap and water. Get medical
advice if irritation develops.
Eye Contact: Wash thoroughly with running water. Get medical advice
if irritation develops.
5.
Fire Fighting Measures
Fire: As with most organic solids, fire is possible at elevated
temperatures or by contact with an ignition source. Minimum dust
cloud ignition temperature: 550C (1022F)
Explosion: Essentially no hazard as dust (Vendor/Bureau of Mines
Relative Rating Scale). No explosion detected up to 200 g/cu.
ft. air.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam,
or carbon dioxide.
Special Information: In the event of a fire, wear full protective
clothing and NIOSH-approved self-contained breathing apparatus
with full facepiece operated in the pressure demand or other positive
pressure mode.
6.
Accidental Release Measures
Ventilate area of leak or spill. Wear appropriate personal protective
equipment as specified in Section 8. Spills: Sweep up and containerize
for reclamation or disposal. Vacuuming or wet sweeping may be
used to avoid dust dispersal. Small amounts of residue may be
flushed to sewer with plenty of water.
7.
Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated
area. Protect against physical damage. Isolate from any source
of heat or ignition. Containers of this material may be hazardous
when empty since they retain product residues (dust, solids);
observe all warnings and precautions listed for the product.
8.
Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: In general, dilution ventilation is a satisfactory
health hazard control for this substance. However, if conditions
of use create discomfort to the worker, a local exhaust system
should be considered.
Personal Respirators (NIOSH Approved): For conditions of use where
exposure to dust or mist is apparent and engineering controls
are not feasible, a particulate respirator (NIOSH type N95 or
better filters) may be worn. If oil particles (e.g. lubricants,
cutting fluids, glycerine, etc.) are present, use a NIOSH type
R or P filter. For emergencies or instances where the exposure
levels are not known, use a full-face positive-pressure, air-supplied
respirator. WARNING: Air-purifying respirators do not protect
workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering
clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash
fountain and quick-drench facilities in work area.
9.
Physical and Chemical Properties
Appearance: White, crystalline powder.
Odor: Odorless.
Solubility: 3 g in 100 g of water
Density: No information found.
pH: 6-7
% Volatiles by volume @ 21C (70F): 0
Boiling Point: Not applicable.
Melting Point: ca. 120C (ca. 248F) Loses water with some decomposition
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.
10.
Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide
may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.
11.
Toxicological Information
No
LD50/LC50 information found relating to normal routes of occupational
exposure.
--------\Cancer
Lists\---------
---NTP Carcinogen---
Ingredient---------- Known -----Anticipated
---IARC ---Category
Calcium Gluconate- (299-28-5)-----
No ------------No------
None
12.
Ecological Information
Environmental Fate: No information found.
Environmental Toxicity: No information found.
13.
Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed
in an appropriate and approved waste disposal facility. Processing,
use or contamination of this product may change the waste management
options. State and local disposal regulations may differ from
federal disposal regulations. Dispose of container and unused
contents in accordance with federal, state and local requirements.
14.
Transport Information
Not regulated.
15.
Regulatory Information
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- -----
---------
Calcium Gluconate (299-28-5) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ----
-----
Calcium Gluconate (299-28-5) Yes Yes No Yes
--------\Federal, State & International Regulations - Part
1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Calcium Gluconate (299-28-5) No No No No
--------\Federal, State & International Regulations - Part
2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Calcium Gluconate (299-28-5) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: No Chronic: No Fire: Yes Pressure: No
Reactivity: No (Pure / Solid)
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